

If you are the owner of all the copyright (you are if you can choose license), then you can use your work in multiple places regardless if you released it as GPL in one place, you can re-license it under different conditions (eg. using it at work).
There have been cases (see Nexuiz) that the copyright holder of a GPL project has accepted money from a company to allow them to use it. This is one of the reasons why the FSF recommends assigning the copyright of GPL projects to the FSF itself, instead of to an individual.

Most of Qt is licensed under the LGPLv3, not the GPLv3. This makes it possible for even proprietary software to include those libraries without needing to make the whole thing copyleft.
I was referring rather to situations in which a company wants to make modifications to the software and not share the changes.